Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields
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Beschreibung
This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing.
This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride–water complex.
The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.
This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing.
This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride–water complex.The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.
Presents the experimental manipulations of molecular states with electrostatic fields which were previously unexplored due to the limitation in the strength of applicable fields Discusses how the static spectra can be decrypted to provide dynamical information of molecules with the aid of external fields: DC-IR 2-dimensional spectroscopy Highlights the concept of large protonic polarizability which underlies the understanding of the behavior of proton in aqueous solutions
Autor*in
Youngwook Park
Themen in »Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields«
Manipulation of Molecules Ice Film Nanocapacitor Reflection–Absorption Infrared Spectroscopy Homogeneous Electrostatic Fields Electric Field-Control Large Protonic Polarizability