Table of Contents – Volume 1
Lead and Zinc
HSE practics
Lead them, but don’t lead them – Lead in analytics and blood lead 5
analytics at Aurubis
Dr. rer. nat. Martin Beran
Metals – an update on managing occupational health risks 17
Dr. Margot Lakemeyer
Practical solutions for minimizing the Cd occupational exposure risk 19
in the Zn/Cd industry
Dr. Noömi Lombaert, Dr. Frank Van Assche, Ir. Mik Gilles
Mobility in Ground-water Environment of ZnS Contained in 31
Pyrometallurgical Zn-Pb Dust
Katarzyna Nowinska, Zdzislaw Adamczy
Current situation and development of regulatory activities 41
Dipl.-Ing. Stefan Buch
By-product treatment and strategic metals recovery technologies
Recovery of lead in copper smelters of KGHM Polska Miedz S.A. 53
Ryszard Prajsnar, Józef Czernecki, Zbigniew Gostynski, Robert Bialy
Sustainable ways to recycle metallurgical residues in the 21st century 65
Dipl.-Ing. Dr.mont. Christoph Pichler and Doz. Dipl.-Ing. Dr.mont Jürgen Antrekowitsch
Feasibility Study on Recycling Lead from Lead Glass through 75
Lead Smelting Process
Zhe-nan Jin, Jian-fang Lv, Hong-ying Yang, Lin-Lin Tong, Guo-Bao Chen, Jun-peng Wang
Metals Recovery of Cements – Juiz de Fora, Brazil 87
Ing. Sérgio de A. Penchel Jr, M.Sc. Tone Takayama, Ing. Maria José Dias, Ing. Livia Mello
Outsourcing of lead and zinc by-product treatment: A win-win-win scenario 97
Colton E. Bangs, Christina E.M. Meskers, Dimitri Van Uytfange, Stijn Foerier
Hydrometallurgical Recovery of Manganese, Zinc and Lead from 109
Pyrometallurgy Sludge
Ph.D. Student Julien Mocellin, Ph.D. Guy Mercier, Ph.D. Jean-Louis Morel,
Ph.D. Jean-François Blais, Ph.D Marie-Odile Simonnot
Recycling potential of precious metals from zinc, lead and 121
copper containing residues
Dipl.-Ing. Dr. mont. Stefan Steinlechner, Dipl.-Ing. Dr. mont. Jürgen Antrekowitsch
Development of Secondary Antimony Oxides for the Application 139
in Plastic Products
M.Sc. Florian Binz, Prof. Dr. Ing. Dr. h.c. Bernd Friedrich
A case study on indium recovery from by-product lead alloy 147
Andrzej Chmielarz, Ryszard Prajsnar, Zbigniew Szolomicki, Ksawery Becker,
Waldemar Pietrek
The Improvement of Bismuth Recovery 159
F. Ogino, T. Fukaya, M. Nishiwaki
ECOLEADTM process: a clean technology to recover Lead 171
and Silver from residues.
E. Pecharromán, C. Álvarez, M. Frades, M.T. Pinedo, G. Díaz, A. Staley,
J. Pusateri, E. Johnson
30 years of recycling of Zinc and Lead Bearing Materials 185
at HYDROMETAL (Belgium).
Philippe Henry
Treatment of complex scrap at Metallo-Chimique 191
M. Chintinne, S. Smets, B. Coletti, C. Geenen
Zinc and lead mines and ores aspects
Selective comminution for pre-concentration at mineral processing 203
Dipl.-Ing. Max Hesse, Prof. Dr.-Ing. Holger Lieberwirth
Selective Flotation Optimization of Sphalerite from Lead and 213
Zinc Ore Complex (sulphide-oxide)
Masoud Kashani, Hossein Zarei, Mehdi Safari
The Mineral Processing Study for a Cu-Pb-Zinc Ore with Carbon 227
Rongsheng Wang, Chuanbing Yu, Bingzi Zhou, Mingan Wei, Lei Song
Lead
Aspects of modern primary Lead smelting technologies
Lead ISASMELT™ Operations at Ust-Kamenogorsk 245
A. S. Burrows, T. Azekenov, R. Zatayev
Drying Blended Concentrates by Kumera Steam Dryer 257
for Kivcet Lead Flash Smelting
Shaolong Chen, Carl-Gustav Berg, Hannu Mansikkaviita, Wang Dezi, Zhang Rong
Isasmelt™-based Reconstruction of a Lead Plant 267
Dr.-Ing. Andrej Avrachov, Dipl.-Ing. Pavel Saltykov,Dipl.-Ing. Jörg J. F. Strecker,
Dr.-Ing. Albin Dobersek, Dipl.-Ing. Turarbek A. Azekenov, Dr.-Ing. Sergey N. Moskalenko
The Research and Engineering Practice of the Lead Oxygen-enriched 273
Flash Smelting
Chengyan Wang, Fei Yin, Wei Gao, Baozhong Ma
Upgrade of QSL Furnace Pulverised Coal Feed at Korea Zinc 285
M. E. Coleman
Secondary Lead production
Development of Polypropylene Recycling from Lead Acid Batteries 301
for Blast Furnace Operation
Zdenek Kunicky
Improvements in Secondary Lead Smelting 307
M. Maccagni, J. Nielsen
Energy consideration at MRU GmbH in Freiberg – a lead recycler with 317
integrated hazardous waste incinerator and plastic compounding
Dr.-Ing. M. Fischer, Dr.-Ing. L. Raabe
Lead refining, downstream processing and applications
Operational Improvements at Kosaka Lead Refinery 329
K. Nishigaki, S. Nakagawara, K. Ichiya
The Optimization of Takehara Lead Refinery Operation 345
Makoto Hamamoto, Kazuya Hatcho, Makoto Narita, Shintato Udo,
Hironaga Okano, Masashi Tottori
Electrolytic Refining of Lead from Secondary Material using 361
Sulfamate Electrolyte
Kota Nakashima, Shojiro Usui, Hidetoshi Sasaoka
Effect of Various Conditions in the Lead Electrolytic Process 375
Takayuki Kitano, Nobuhiro Shima, Naoki Hashimoto
Lead oxide battery grade synthesis via formation and decomposition 389
of lead citrate
Dr.-Ing. Srecko Stopic, Dipl.-Ing. Thomas Träger, Prof. Dr.-Ing. Dr. h. c. Bernd Friedrich
Lead Process fundamentals, modelling and new processes
The FLUBOR® Process: Pilot Tests Results 399
M. Maccagni, J. Nielsen, T. Hymer
The Lead Acid Battery Paste Electrowinning with the FAST Pb Process 407
M. Maccagni, J. Nielsen
Wear of Refractory Linings in the Lead and Zinc Industry 415
Dr. Dean Gregurek, Dr. Christian Majcenovic, Dr. Christine Wenzl, Ing. Alfred Spanring
Thermo mechanical analysis of a Lead-rotary furnace with 427
Finite Element Simulation
H. U. Marschall, D. Kreuzer, A. Spanring
Computer Fluid Dynamic simulations of the tapping process in a 441
lead short rotary furnace
Wagner Moulin Silva, Bruno Augusto Batista Ribeiro
Understanding matte formation using the Ellingham diagram for sulphides 451
Dr. Sander Arnout, Dr. Els Nagels
The Lead Anode in Galvano Technique – A High Tech Operating Resource? 461
Bernd Böttcher, Wolfgang Bähre, Dr. Franz Martin Knoop
Lead downstream processing and applications
Future Requirements for Lead Based Materials in the Battery Industry 477
Timothy W. Ellis, R. David Prengaman
The Need for the Sustainable and Responsible Recycling of Lead 483
Brian K. Wycklendt, Dr. Frank Toubartz
European Lead Oxide Market – Trends in Demand and Consequences for the 491
Oxide Producers
David Hardy
Table of Contents – Volume 2
Zinc
Aspects of modern Zink production technologies
Evaluating Supply and Demand Trends in the Zinc Market 505
Ulrike Dorner
Zinc and Lead smelting at Hachinohe Smelter 517
A. Sugawara
Improvement of Zinc Electrolytic Process 527
Hiroyuki Minami,Yuji Shimizu, Takuhiro Yamaguchi
The Outotec® Direct Zinc Smelting Process 537
Jacob Wood, Dr. James Coveney, Gu Helin, Lan Xu, Song Xincheng
Flotation and Hydroprocessing of Bulk Concentrates from Las Cruces Mine 549
C. Frias, E. Vera, A. Romero, J. Blanco
Leach-Electrowinning of Zinc from Abakaliki Complex Sulphide Ore 561
Olawale Olarewaju Ajibola, Daniel T. Oloruntoba, Adebayo Felix Owa
Zinc concentrate roasting and leaching
A New Process for the Full Recovery of Zinc and Other Valuable Metals 579
from Zinc Concentrates
Francisco Tamargo, Sushil Bhatter
Process Modification to Increase the Amount of Fine Concentrates 593
by Wet Feed Type Roaster in Hikoshima Zinc Smelter
T. Yoshida, A. Nishijima, T. Ono, F. Nishiyama, T. Baba
Formation of molten sulfide phase in systems related to zinc sulfide roasting 601
Dr. Hannu Johto, Prof. Dr. Pekka Taskinen, Dr. Maija-Leena Metsärinta
Effect of Transition Metal Impurities on Phase and Microstructure during 613
the Oxidizing Roasting of ZnS Powder
Hiromichi Takebe, Satoshi Okano, Takahiko Oukura
Process and Cost Optimized Agitator Solutions for Hydrometallurgical 621
Base Metals Processing
Jochen Jung, Wolfgang Keller
Deposition of hematite from zinc sulphate solution 645
Jari Aromaa, Lauri Rusanen, Olof Forsén
Pressure Leaching of Marmatite Concentrate with Lignite Coal as 655
Elemental Sulfur Disperser
Zhifeng Xu, Yuanjun Lan, Kaixi Jiang
The effects of present ions in lead sulfate halide leaching from zinc 667
leaching plant residual cake
Hossein Zarei, Mehdi Safari, Mohammad Abdi, Mehrnoosh Heydari
Zinc solvent extraction
Zinc Calcine Treatment by ZINCEXTM Solvent Extraction based process 687
G. Díaz, J. Calvo, Ch. Onoberhie, F. Sánchez, M. Pérez, E. Vírseda, R. Parra
Synergistic extraction and separation of Fe (III) and Zn (II) using 705
TBP and D2EHPA
Atefeh Azizi, Fereshteh Rashchi, Ataollah Babakhani, Mehdi Noori
Effect of citrate on solvent extraction of zinc by D2EHPA 713
Diankun Lu, Yongfeng Chang, Wei Wang, Shanrong Zhao, Feng Xie
Zinc electrowinning
Seasonal Effects on the Water Balance in a Zinc Electrowinning Cell House 727
Michael Mahon, Dr. Akram Alfantazi
Synergistic Effect of Gelatin and Sb on Deposition Behavior and 739
Texture of Zn in Electrowinning
Prof. Dr. Eng. Hiroaki Nakano, Hiromitsu Yamashita, Satoshi Oue,
Prof. Emeritus Dr. Eng. Hisaaki Fukushima, Nobuyoshi Sogabe
Electrodeposition of the MnO2 Layer on Lead-Based anodes in the 755
Zinc Electrowinning Process
Maysam Mohammadi, Michael Mahon, Akram Alfantazi
Amorphous Oxide Coated Titanium Anode, MSA®, for Energy-Efficient 771
Zinc Electrowinning without Manganese Oxide Deposition
Masatsugu Morimitsu, Tian Zhang, T. Masashi Ueda
The Effect of the Current Density Change on the Beta-PbO2 Oxide 779
Layer Formed on the Pb-Ag Anode for Zinc Electrowinning
Yasushi Takasaki, Shigeru Kawamura, Kazutoshi Haga, Atsushi Shibayama,
Ryo Inoue, Rie Sato, Kazunari Suzuki
Zinc recovery from EAF dust treatment
EAF Dust and Secondary Fly Ash Treatment by MF Process at Miike Smelter 791
K. Fujioka, S. Hatae
Crude zinc oxide production from steel mill dusts with the RecoDust process 799
Dipl.-Ing. Bernhard Geier, Univ. Prof. Dipl.-Ing. Dr. techn. Harald Raupenstrauch,
Dipl.-Ing. Karl Pilz
Submerged plasma technology and work within Zn/Pb recovery 807
Bror Magnus Heegaard, Maria Swartling, Matej Imris
Improvements of The Production Process of Zinc Oxide from 817
Electric Arc Furnace Dust
Kenji Numata, Seiichi Karasawa
Recovering crude zinc oxide from EAF dust at Shisaka Smelting Co., LTD 831
S. Komori, H. Fujiyama, H. Watanabe, K. Tomoda
The INDUTEC® Process: Converting Waste into Saleable Products 843
M. Maccagni, J. Nielsen
New Approach to Recover Metallic Zinc from EAF Dust by CaO Treatment 849
R. Chairaksa-Fujimoto, T. Nagasaka
Recycling of EAF dusts with waste plastics 865
Mariusz Grabda, Sylwia Oleszek, Etsuro Shibata, Takashi Nakamura
Sustainable Recovery of Heavy Metals from 877
Metallurgical Dust – the 2sDR process
Dr. Gernot Rösler, Dr. Christoph Pichler, Dipl.-Ing. Stefan Wegscheider
Priv. Doz. Jürgen Antrekowitsch
The Waelz Process – Worldwide Most Used Process for the Recycling 887
of Zinc Containing Residues
Dipl.-Ing. Andreas Ruh, Dipl.-Ing. Dae-Soo Kim
Zinc and iron recovery from filter dust by melt bath injection 903
into an induction furnace
Dipl.-Ing. Gerald Stubbe, Dr.-Ing. Carsten Hillmann, Dipl.-Ing. C. Wolf
Hydrometallurgical zinc production from fume oxides 917
Björn Saxén, Marko Lahtinen
Treatment of Secondary Raw Materials at Juiz de Fora Zinc Smelter in Brazil 931
Tone Takayama, Walter Magalhães, Fabiano Mariel dos Santos
Mineralogical Characterization from the Waelz Circuit – Juiz de Fora, Brazil 953
Ing. Livia da Silva Mello, M.Sc. Mariana Gazire Lemos, Ing. Fabiana Maria Teixeira,
M.Sc. Maria José Dias, M.Sc. Tone Takayama Filho, PhD. Paola Ferreira Barbosa
Research and Development of Metallurgcal Wastes Recycling with 965
Recovery of Zinc, Lead and Tin
Dr. P. Kozlov, R. Shakirzyanov, A. Zatonsky, Dr. A. Panshin
Reductive power of different carbon materials 977
Dr. Els Nagels, Dr. Sander Arnout, An Serbruyns
Zinc downstream processing, applications and secondary smelting
Zinc Phosphating for Safety Enhancement of Carbon Steels in 989
Chloride Environment
D. T. Oloruntoba, A P I Popoola
Multistage removal of aluminium from secondary zinc – a challenge 999
in zinc recycling
Dr.-Ing. Daniel Schmitz; Dipl.-Ing. Bodo Schauries
Bio Leaching
Innovative Conditioning Approaches for Underground In-situ 1013
Bioleaching Applications
Dipl.-Eng Ralf Schlüter, Prof. Helmut Mischo
Batch and Continuous bioleaching of zinc sulphide concentrates 1025
with moderate thermophiles
Pablo. S. Pina, Adelson D. Souza, Versiane A. Leão
Surface Complexation Modelling for Zn(II) Removal by Aluminium 1037
Hydroxide from AMD
Dr. Chiharu Tokoro, M.E. Taisuke Sakakibara, M.E. Shinya Suzuki, B.E. Shinichi Muto
Zinc Process fundamentals, modelling and new processes
A Hydrometallurgical Process to produce Zinc from Both Primary 1055
and Secondary Sources
M. Maccagni, J. Nielsen, T. Hymer
Using Concentrated Solar Radiation in Zinc Metallurgy 1063
Dr. Christian Wieckert, Nikolaos Tzouganatos
Development of the “Pb Less” Electrolytic Zinc Technology 1077
Hirofumi Nakamura, Koji Yamada, Taro Aichi
Effective Front End Loading of projects to support equipment selection 1087
and flow sheet optimisation
Dr. Ross Cooper, Brenden O’Shea
The Process Simulation and Control Optimization of the 1103
Lead Sintering Roasting Process
Teresa Rojas-Sánchez, Antonio Romero-Serrano, Aurelio Hernández-Ramírez,
Isaías Almaguer-Guzmán, Ricardo Benavides-Pérez, Manuel Flores-Favela
Poster
Development of a lead-free brass alloy 1114
Thomas Angerer, Sigurd Hofer
Synergistic extraction and separation of Fe (III) and Zn (II) using 1116
TBP and D2EHPA
Dipl.-Ing. Atefeh Azizi, Prof. Dr.-Ing. Fereshteh Rashchi, Dipl.-Ing. Ataollah Babakhani,
Dipl.-Ing. Mehdi Noori
Identification of permanent magnets 1118
Dipl.-Ing. Laura Benedek
Study of phase equilibria and freeze linings in novel 1120
high temperature processes
Tijl Crivits, Peter Hayes, Evgueni Jak
Characterization and Recycling of Silicon PV Modules 1122
Eng. Pablo Ribeiro Dias, Mariana Gonçalves Benevit, Dr. Hugo Marcelo Veit
Wet chemical decoating of metal cutting tools 1124
Tamara Ebner, Gregor Kücher
LCD Screens – Indium Characterization 1126
Msc. Adjanara Preis Gabriel, Priscila Hiromi Yamazaki, Dr. Hugo Marcelo Veit
Characterisation and Thermal Behaviour of Indonesian Copper Sulphides 1128
for Leaching Process
Imelda Hutabarat, MSc.
Alloying Elements and Heat Treatment on Wrought 7xxx Aluminium Alloys 1130
Dipl.-Ing. Gernot Kolb, Univ.-Prof. Dipl.-Ing. Dr. mont. Helmut Antrekowitsch
Solvent extraction and separation of cobalt and lithium using 1132
D2EHPA and Cyanex 272
Dipl.-Ing. Sara Mahmoodi, Prof. Dr.-Ing. Fereshteh Rashchi, Dipl.-Ing. Mehdi Noori,
Dipl.-Ing. Ataollah Babakhani
Optimization of Vanadium Recovery from Power Plants Fly Ash in 1134
Alkaline Media
Dipl.-Ing. H. Nourizadeh, Prof. Dr.-Ing. F. Rashchi, Dipl.-Ing. S. M. J. Mirazimi, Dipl.-Ing. S. M. M. Noori
Influence of Electrolysis Parameter on the Co-Deposition of Impurities 1136
during Silver Electrorefining
Dipl.-Ing. A. Pophanken; Prof. Dr.-Ing. Dr. h.c. B. Friedrich, Dr. Wolfgang Koch
Anodizing of Recycling Aluminium 1138
DI Carina Maria Schlögl, Univ.-Prof. DI Dr.mont. Helmut Antrekowitsch
Effects of pyrolysis on the metallurgical processing of waste electrical 1140
and electronic equipment
Dipl.-Ing. Christoph Sorger
Recycling of Residues from the Copper Industry 1142
Dipl.-Ing. Stephan Steinacker
Recycling of Nd2Fe14B-Magnets 1144
Dipl.-Ing. Philipp Stuhlpfarrer
Innovative utilization of steel mill dust for the creation of secondary 1146
raw materials-2sDR process
Dipl.- Ing. Stefan Wegscheider
Rapid artificial aging of Al-Mg-Si alloys 1148
Marion Werinos, Helmut Antrekowitsch, Stefan Pogatscher
Optimization of a Dialysis Process for the recycling of gallium 1150
O. Zeidler, C. Scharf, M. Stelter
Recycling of aluminium powdered waste 1152
Marlis Zöhrer, Thomas Angerer
Authors Index 1157
Keywords Index 1143
Ulrich Waschki