In crystals as diverse as sodium chloride, silicon dioxide,
sold xenon, pyrene, arsenic triselenide, and silver
chloride, the fundamental electronicexcitation (exciton) is
localized within its own lattice distortion field very
shortly after its creation. This book discusses the
structure if the self-trapped exciton (STE) and its
evolution along the path of its return to the ground state
or to a defect state of crytal. A comprehensive review of
experiments on STEs in a wide range of materials has been
assembled, including extensive tables of data. Throughout,
emphasisis given to the basic physics underlying various
manifestations of self-trapping. The role of the spontaneous
symmetry-breaking or "off-center"relaxation in STE
structure is examined thoroughly, and leads naturally to the
subject of lattice defect formation as a product of STE
relaxation. The theory of STEs is developed from a
localized, atomistic perspective using self-consistent
methods adapted from the theory of defects in solids. At
this time of rapid progress in STEs, researchers will
welcome the first monograph dedicaded solely to this topic.
Self-Trapped Excitons describes the structure and evolution of self-trapped excitons in a wide variety of materials. It includes a discussion of the theory, a comprehensive review of experiments, and extensive tables of data. At this time of rapid progress in the field, researchers will welcome this first monograph dedicated solely to self-trapped excitons.
Y. Toyozawa
Absorption Atom Diffusion Sorption crystal crystal structure electron exciton kinetics microscopy polarization scattering spectroscopy structure synchrotron radiation