Electrode-Electrolyte Interphases in Solid-State Batteries
A Concise Understanding at the Nanoscale
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Beschreibung
This brief volume offers a focused and accessible overview of electrode-electrolyte interphases in solid-state batteries, emphasizing their formation, composition, and critical influence on battery performance and longevity. It examines the thermodynamic, kinetic, and mechanistic aspects of interphase development across different classes of solid electrolytes while exploring how operating conditions such as temperature, pressure, and electro-chemo-mechanical coupling drive their evolution under realistic environments. The book highlights the dual role of these interphases as both enablers and constraints, discussing their impact on ion transport, interfacial stability, resistance growth, and failure mechanisms, including dendrite formation. It also presents state-of-the-art nanoscale characterization techniques including in-situ, operando, ex-situ and computational approaches used to investigate interphase structure, dynamics, and transport phenomena. Complemented by an overview of interfacial engineering strategies aimed at improving stability and mitigating degradation, this concise volume is designed to support researchers and students in understanding, designing, and controlling interphases for high-performance, durable solid-state energy storage systems.
This brief volume offers a focused and accessible overview of electrode-electrolyte interphases in solid-state batteries, emphasizing their formation, composition, and critical influence on battery performance and longevity. It examines the thermodynamic, kinetic, and mechanistic aspects of interphase development across different classes of solid electrolytes, while exploring how operating conditions such as temperature, pressure, and electro-chemo-mechanical coupling drive their evolution under realistic environments. The book highlights the dual role of these interphases as both enablers and constraints, discussing their impact on ion transport, interfacial stability, resistance growth, and failure mechanisms, including dendrite formation. It also presents state-of-the-art nanoscale characterization techniques including in-situ, operando, ex-situ and computational approaches used to investigate interphase structure, dynamics, and transport phenomena. Complemented by an overview of interfacial engineering strategies aimed at improving stability and mitigating degradation, this concise volume is designed to support researchers and students in understanding, designing, and controlling interphases for high-performance, durable solid-state energy storage systems.
Provides a concise review on solid-state electrolytes-based interphases Shows a unified connection of solid-state interphasial science, nanoscale characterization and engineering strategies Integrates advanced operando, in-situ, ex-situ with theoretical studies, and presents multi-interphasial chemistries
Autor*in
Huaiyu Shao
Themen in »Electrode-Electrolyte Interphases in Solid-State Batteries«
Solid-electrolyte interphases Space charge layers Electro-chemo mechanical effect Charge transfer Solid-state batteries Energy density Interphase engineering Artificial SEI Working voltage window Mono and Multivalent cations In-situ and Operando characterization