Heterocycles from Carbenes and Nitrenes

Beschreibung

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.


This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.
The uses of carbene and nitrene species in the generation of traditional and novel heterocyclic compounds. Multiple methods to enter carbene and nitrene species for heterocyclic syntheses. Carbene-generated products as precursors to heterocycles.

Autor*in

Michael P. Doyle

Themen in »Heterocycles from Carbenes and Nitrenes«

Heterocyclic synthesis Carbene precursors Nitrenes precursors C-H/X-H insertions Cycloadditions

Stimmen zu »Heterocycles from Carbenes and Nitrenes«

Details

Link teilen