Molecular Encapsulation
Organic Reactions in Constrained Systems
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Beschreibung
The inclusion of small guest molecules within suitable hostcompounds results in constrained systems that imbue novelproperties upon the incarcerated organic substrates. Supramoleculartactics are becoming widely employed and this treatise spotlightsthem. Often, the impact of encapsulation on product formation issubstantial. The use of constrained systems offers the means tosteer reactions along desired pathways. A broad overview of varioussupramolecular approaches aimed to manipulate chemical reactionsare featured.
The following topics are covered in detail:
- general concepts governing the assembly of the substrate withthe reaction vessel
- preparation of molecular reactors
- stabilization of reactive intermediates
- reactions in water, in organic solvents, and in the solidstate
- photochemical reactions
- reactions with unusual regioselectivity
Molecular Encapsulation: Organic Reactions in ConstrainedSystems is an essential guide to the art of changing theoutcome and the selectivity of a chemical reaction using nano-sizedreaction vessels. It will find a place on the bookshelves ofstudents and researchers working in the areas of supramolecularchemistry, nanotechnology, organic and pharmaceutical chemistry,and materials science as well.
Autor*in
Udo H. Brinker
Themen in »Molecular Encapsulation«
Chemie Chemistry Nanomaterial Nanomaterialien Nanomaterials Nanostrukturiertes Material Nanotechnologie Nanotechnology Organische Chemie Supramolecular Chemistry Supramolekulare Chemie
Stimmen zu »Molecular Encapsulation«
"The book has a broad scope and serves its purpose very well foreveryone who is interested in the preparation of molecularreactors, the stabilization of reactive intermediates, reactions ofunusual regioselectivity, confined photochemical reactions, orsupramolecularly enhanced reactions in water, organic solvents, orthe solid state. Thus, the book is well suited both for beginnersand for experts, and it is an essential addition to the bookshelfof a supramolecular chemist." (Angewandte Chemie, 1 February 2011)
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